Three golden rules for an insightful interview.
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Ask your questions in (chrono)logical order
If you're used to interviewing people for print, you probably take the liberty of asking the questions in the order they jump into your mind and rearrange them when you write your story. When you do an interview podcast, you must help the subject tell a story by asking in order.

Shut up
Most of us have the habit of saying little words of encouragement as other people talk, such as “yeah” or “cool.” This sounds awful on a podcast. Just listen while your subject talks.

Put your subject at ease
Many people have never given a recorded interview, let alone on a podcast. They have no idea what to expect. Tell them the simple stuff (e.g. your show's not live) and say what you're looking for. If you encourage your guests to illustrate their points with tangible stories, it will make a big difference.
